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61.
Katharina Marquardt Elena Petrishcheva Rainer Abart Emmanuel Gardés Richard Wirth Ralf Dohmen Hans-Werner Becker Wilhelm Heinrich 《Physics and Chemistry of Minerals》2010,37(10):751-760
In this study, we address volume diffusion of ytterbium in yttrium aluminum garnet (YAG) using thin-film single crystal diffusion
couples. We employ analytical transmission electron microscopy (ATEM) as a tool for combined microstructural and microchemical
analysis and compare the results to Rutherford backscattering (RBS) analysis. Given the high spatial resolution of the method,
we focus on microstructural changes of the thin-film diffusant source during the diffusion anneal. We evaluate the potential
influence of the associated changes in its transport properties on the evolution of concentration profiles in the single crystal
substrate. This approach allows us to test the reliability of determination of volume diffusion coefficients from thin-film
diffusion experiments. We found that for the chosen experimental setting, the influence of thin-film re-crystallization is
small when compared with the experimental uncertainty and good estimates for the volume diffusion coefficients of Yb in YAG
can be obtained using standard assumptions. Both Yb-concentration profiles analyzed with ATEM and with RBS give similar results.
At 1,450°C and 1 bar, we infer log D
Yb (m2/s) values of −19.37 ± 0.07 (TEM) and −19.84 ± 0.02 (RBS). Although the change in thin-film transport properties associated
with successive crystallization during the diffusion anneal does not play a major role for our experimental setup, this effect
cannot generally be ignored. 相似文献
62.
Nitrate monitoring is commonly conducted with low-spatial resolution, only at the outlet or at a small number of selected locations. As a result, the information about spatial variations in nitrate export and its drivers is scarce. In this study, we present results of high-spatial resolution monitoring conducted between 2012 and 2017 in 65 sub-catchments in an Alpine mesoscale river catchment characterized by a land-use gradient. We combined stable isotope techniques with Bayesian mixing models and geostatistical methods to investigate nitrate export and its main drivers, namely, microbial N turnover processes, land use and hydrological conditions. In the investigated sub-catchments, mean values of NO3− concentrations and its isotope signatures (δ15NNO3 and δ18ONO3) varied from 2.6 to 26.7 mg L−1, from −1.3‰ to 13.1‰, and from −0.4‰ to 10.1‰, respectively. In this study, land use was an important driver for nitrate export. Very strong and strong positive correlations were found between percentages of agricultural land cover and δ15NNO3, and NO3− concentration, respectively. Mean proportional contributions of NO3− sources varied spatially and seasonally, and followed land-use patterns. The mean contribution of manure and sewage was much higher in the catchments characterized by a high percentage of agricultural and urban land cover comparing to forested sub-catchments. Specific NO3− loads were strongly correlated with specific discharge and moderately correlated with NO3− concentrations. The nitrate isotope and concentration analysis results suggest that nitrate from external sources is stored and accumulated in soil storage pools. Nitrification of reduced nitrogen species in those pools plays the most important role for the N-dynamics in the Erlauf river catchment. Consequently, nitrification of reduced N sources was the main nitrate source except for a number of sub-catchments dominated by agricultural land use. In the Erlauf catchment, denitrification plays only a minor role in controlling NO3− export on a regional scale. 相似文献
63.
Three‐dimensional receiver ghost attenuation (deghosting) of dual‐sensor towed‐streamer data is straightforward, in principle. In its simplest form, it requires applying a three‐dimensional frequency–wavenumber filter to the vertical component of the particle motion data to correct for the amplitude reduction on the vertical component of non‐normal incidence plane waves before combining with the pressure data. More elaborate techniques use three‐dimensional filters to both components before summation, for example, for ghost wavelet dephasing and mitigation of noise of different strengths on the individual components in optimum deghosting. The problem with all these techniques is, of course, that it is usually impossible to transform the data into the crossline wavenumber domain because of aliasing. Hence, usually, a two‐dimensional version of deghosting is applied to the data in the frequency–inline wavenumber domain. We investigate going down the “dimensionality ladder” one more step to a one‐dimensional weighted summation of the records of the collocated sensors to create an approximate deghosting procedure. We specifically consider amplitude‐balancing weights computed via a standard automatic gain control before summation, reminiscent of a diversity stack of the dual‐sensor recordings. This technique is independent of the actual streamer depth and insensitive to variations in the sea‐surface reflection coefficient. The automatic gain control weights serve two purposes: (i) to approximately correct for the geometric amplitude loss of the Z data and (ii) to mitigate noise strength variations on the two components. Here, Z denotes the vertical component of the velocity of particle motion scaled by the seismic impedance of the near‐sensor water volume. The weights are time‐varying and can also be made frequency‐band dependent, adapting better to frequency variations of the noise. The investigated process is a very robust, almost fully hands‐off, approximate three‐dimensional deghosting step for dual‐sensor data, requiring no spatial filtering and no explicit estimates of noise power. We argue that this technique performs well in terms of ghost attenuation (albeit, not exact ghost removal) and balancing the signal‐to‐noise ratio in the output data. For instances where full three‐dimensional receiver deghosting is the final product, the proposed technique is appropriate for efficient quality control of the data acquired and in aiding the parameterisation of the subsequent deghosting processing. 相似文献
64.
Jessica Barabasch Mathieu Ducros Nicolas Hawie Samer Bou Daher Fadi Henri Nader Ralf Littke 《Basin Research》2019,31(2):228-252
The Eastern Mediterranean Levant Basin is a proven hydrocarbon province with recent major gas discoveries. To date, no exploration wells targeted its northern part, in particular the Lebanese offshore. The present study assesses the tectono‐stratigraphic evolution and related petroleum systems of the northern Levant Basin via an integrated approach that combines stratigraphic forward modeling and petroleum systems/basin modeling based on the previous published work. Stratigraphic modeling results provide a best‐fit realisation of the basin‐scale sedimentary filling, from the post‐rift Upper Jurassic until the Pliocene. Simulation results suggest dominant eastern marginal and Arabian Plate sources for Cenozoic siliciclastic sediments and a significant contribution from the southern Nilotic source mostly from Lower Oligocene to Lower Miocene. Basin modeling results suggest the presence of a working thermogenic petroleum system with mature source rocks localised in the deeper offshore. The generated hydrocarbons migrated through the deep basin within Jurassic and Cretaceous permeable layers towards the Latakia Ridge in the north and the Levant margin and offshore topographic highs. Furthermore, the basin model indicates a possibly significant influence of salt deposition during Messinian salinity crisis on formation fluids. Ultimately, the proposed integrated workflow provides a powerful tool for the assessment of petroleum systems in underexplored areas. 相似文献
65.
Regional mean sea level changes in the German Bight are considered. Index time series derived from 15 tide gauge records are
analysed. Two different methods for constructing the index time series are used. The first method uses arithmetic means based
on all available data for each time step. The second method uses empirical orthogonal functions. Both methods produce rather
similar results for the time period 1924–2008. For this period, we estimate that regional mean sea level increased at rates
between 1.64 and 1.74 mm/year with a 90% confidence range of 0.28 mm/year in each case. Before 1924, only data from a few
tide gauges are available with the longest record in Cuxhaven ranging back till 1843. Data from these tide gauges, in particular
from Cuxhaven, thus receive increasingly more weight when earlier years are considered. It is therefore analysed to what extent
data from Cuxhaven are representative for the regional sea level changes in the German Bight. While this cannot be clarified
before 1924, it is found that this is not the case from 1924 onwards when changes in Cuxhaven can be compared to that derived
from a larger data set. Furthermore, decadal variability was found to be substantial with relatively high values towards the
end of the analysis period. However, these values are not unusual when compared to earlier periods. 相似文献
66.
Ludovic Puig Göran Pilbratt Astrid Heske Isabel Escudero Pierre-Elie Crouzet Bram de Vogeleer Kate Symonds Ralf Kohley Pierre Drossart Paul Eccleston Paul Hartogh Jeremy Leconte Giusi Micela Marc Ollivier Giovanna Tinetti Diego Turrini Bart Vandenbussche Paulina Wolkenberg 《Experimental Astronomy》2018,46(1):211-239
ARIEL, the Atmospheric Remote sensing Infrared Exoplanet Large survey, is one of the three M-class mission candidates competing for the M4 launch slot within the Cosmic Vision science programme of the European Space Agency (ESA). As such, ARIEL has been the subject of a Phase A study that involved European industry, research institutes and universities from ESA member states. This study is now completed and the M4 down-selection is expected to be concluded in November 2017. ARIEL is a concept for a dedicated mission to measure the chemical composition and structure of hundreds of exoplanet atmospheres using the technique of transit spectroscopy. ARIEL targets extend from gas giants (Jupiter or Neptune-like) to super-Earths in the very hot to warm zones of F to M-type host stars, opening up the way to large-scale, comparative planetology that would place our own Solar System in the context of other planetary systems in the Milky Way. A technical and programmatic review of the ARIEL mission was performed between February and May 2017, with the objective of assessing the readiness of the mission to progress to the Phase B1 study. No critical issues were identified and the mission was deemed technically feasible within the M4 programmatic boundary conditions. In this paper we give an overview of the final mission concept for ARIEL as of the end of the Phase A study, from scientific, technical and operational perspectives. 相似文献
67.
Mapping global land system archetypes 总被引:1,自引:0,他引:1
Tomáš Václavík Sven Lautenbach Tobias Kuemmerle Ralf Seppelt 《Global Environmental Change》2013,23(6):1637-1647
Land use is a key driver of global environmental change. Unless major shifts in consumptive behaviours occur, land-based production will have to increase drastically to meet future demands for food and other commodities. One approach to better understand the drivers and impacts of agricultural intensification is the identification of global, archetypical patterns of land systems. Current approaches focus on broad-scale representations of dominant land cover with limited consideration of land-use intensity. In this study, we derived a new global representation of land systems based on more than 30 high-resolution datasets on land-use intensity, environmental conditions and socioeconomic indicators. Using a self-organizing map algorithm, we identified and mapped twelve archetypes of land systems for the year 2005. Our analysis reveals similarities in land systems across the globe but the diverse pattern at sub-national scales implies that there are no ‘one-size-fits-all’ solutions to sustainable land management. Our results help to identify generic patterns of land pressures and environmental threats and provide means to target regionalized strategies to cope with the challenges of global change. Mapping global archetypes of land systems represents a first step towards better understanding the global patterns of human–environment interactions and the environmental and social outcomes of land system dynamics. 相似文献
68.
Dust particles, like photons, carry information from remote sites in space and time. From knowledge of the dust particles' birthplace and their bulk properties, we can learn about the remote environment out of which the particles were formed. This approach is called “Dust Astronomy” which is carried out by means of a dust telescope on a Dust Observatory in space. Targets for a dust telescope are the local interstellar medium and nearby star forming regions, as well as comets and asteroids. Dust from interstellar and interplanetary sources is distinguished by accurately sensing their trajectories. Trajectory sensors may use the electric charge signals that are induced when charged grains fly through the detector. Modern in-situ dust impact detectors are capable of providing mass, speed, physical and chemical information of dust grains in space. A Dust Observatory mission is feasible with state-of-the-art technology. It will (1) provide the distinction between interstellar dust and interplanetary dust of cometary and asteroidal origin, (2) determine the elemental composition of impacting dust particles, and (3) monitor the fluxes of various dust components as a function of direction and particle masses. 相似文献
69.
An algorithm for the estimation of root zone soil moisture is presented. Global fields of the soil moisture within the uppermost metre of soil are derived with a temporal resolution of 10 days. For calibration, long-term soil moisture observations from the former Soviet Union are used. The variance of the measurements is largely dominated by the spatial variability of the long-term mean soil moisture, while the temporal variability gives comparatively small contribution. Consequently, the algorithm is organised into two steps. The first step concentrates on the retrieval of the spatial variance of the long-term means, which comprises more than 85% of the total soil moisture variability. A major part of the spatial variance can be explained by four easily available fields: the climatological precipitation, land use, soil texture, and terrain slope. The second step of the algorithm is dedicated to the local temporal variability. This part of variability is recovered by using passive microwave data from scanning multichannel microwave radiometre (SMMR) supported by monthly averaged fields of air temperature and precipitation. The 6-GHz channel of SMMR is shown to be severely disturbed by radio frequency interference, so that information from the 10-GHz channel is used instead. The algorithm provides reasonable soil moisture fields which is confirmed by a comparison with independent measurements from Illinois. 相似文献
70.
Dorthe Pflanz Christoph Gaedicke Ralf Freitag Matthias Krbetschek Nikolay Tsukanov Boris Baranov 《International Journal of Earth Sciences》2013,102(3):903-916
The tectonic position of the Kamchatka Cape Peninsula at the junction of the active Kuril–Kamchatka and Aleutian arcs exposes the coastline of the peninsula to strong neotectonic activities. Fracture zones have variable influence on uplift of the Kamchatka Cape Peninsula. Relevant morphologic indicators of neotectonic activity are multilevel, highly uplifted marine terraces and terraces displaced along active faults. Recent uplift rates of coastal sediments are determined by remote sensing via ASTER and SRTM DEM combined with optically stimulated luminescence dating (OSL). On the Kamchatka Cape Peninsula, terraces from the same generation are mapped at different elevations by remote sensing methods. After defining different areas of uplifted terraces, four neotectonic blocks are identified. According to apatite fission track data, the mean differential exhumation rates range from 0.2 to 1.2 mm year?1 across the blocks since Late Miocene. The OSL data presented point to significant higher uplift rates of up to 3 ± 0.5 and 4.3 ± 1 mm year?1, which indicates an acceleration of the vertical movement along the coast of Kamchatka Cape Peninsula in Upper Pleistocene and Holocene times. 相似文献